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The single bonded O has a negative charge. Missed the LibreFest? You're not going to make a substituted benzene. So guess what? A combination of sulfuric acid and nitric acid is going to react together to make the active electrophile as we'll see later when we go into the mechanism. design multistep syntheses using the reactions discussed in this and the preceding chapters. Regardless of how you draw it, it's really going to produce the same product. Let's just take the first one into account, EAS halogenation. 15 - Analytical Techniques: IR, NMR, Mass Spect, Ch. Another combination that can produce carbocations which be actually BF3, so a strong Lewis acid with alcohol. Some of these agents are going to require catalysts in order to become strong enough for the benzene to react with them. Halogenation would be a reaction with a double bond and a diatomic halogen, so something like X2. Once again, X is only really equal to only bromine and chlorine in these cases. We use your LinkedIn profile and activity data to personalize ads and to show you more relevant ads. It's just that different websites, different textbooks, different professors like to use different combinations. Outline Aromaticity Huckel’s rule The Reactions (Electrophilic Substitution) Halogenation Friedel-Craft’s Reaction Alkylation and acylation Nitration and sulphonation Oxidation and reduction of benzene derivates Disubstitution (Ortho, meta, para directing groups) … 27 times. Ch17 Reactions of Aromatic Compounds (landscape).docx Page7 Nitration of Benzene Benzene will react with hot concentrated nitric acid to produce nitrobenzene. Notes for the CIE O Level Chemistry – 26: Benzene and Its Compounds. Download free Organic Chemistry concept maps here! Check out this reaction map of over 25 different organic chemistry reactions of benzene and related compounds, allowing for easy synthetic planning. Those are the two Friedel-Crafts reactions. The periodic table—the transition metals, Topic 11: Measurement and data processing, 3. Let's see if you can remember all of them! This is going to work for bromine. We need a catalyst, guys. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. If you wish to opt out, please close your SlideShare account. Aromatic compounds are extremely important for all kinds of pharmaceuticals. The most common would be using nitric acid, HNO3, and sulfuric acid. That's what we wanted. We're going to see later how BF3 and alcohol can also produce carbocation-like structures that will react with benzene and produce an R group. Maybe making the next Viagra. Formulae, stoichiometry and the mole concept, 7. To desulfonate it's actually even easier. solve road-map problems that require an understanding of the chemistry discussed in this chapter and those that preceded it. A) a hydroxide ion. It's the most common version. One HNO3 molecule reacts with another one and makes that active electrophile. That Lewis acid catalyst for Friedel-Crafts reactions is going to be an aluminum catalyst, so it's going to be AlX3. 4 months ago. You're just going to use a dilute form of the acid, so you might see it written as dilute H2SO4. Iodine does not – I was going to use a different color. So a carbonyl group. It's evolving an SO3 gas that's going to react. Great job, guys! The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Clipping is a handy way to collect important slides you want to go back to later. It turns out that iodination is a little bit tricky. All Rights Reserved. Organic Chemistry: Benzene and Its Derivates 1.

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